Jennifer R. Krumper

Visiting Assistant Professor

Fall 2009

  • Organic Chemistry I (CHEM 225C)
Phone (207) 725-3015
Title Visiting Assistant Professor
Department CHEMISTRY
Work Location 260 Cleaveland Hall
E-Mail jkrumper@bowdoin.edu
Jennifer Krumper

Education

Ph.D., University of California, Berkeley, CA, 2003
A.B., Bowdoin College, Brunswick, ME, 1998

Previous Academic Positions

University of California, Irvine, CA (2007 – 2009)
NIH Kirschstein-NRSA Postdoctoral Research Fellow

Idaho State University, Pocatello, ID (2004 – 2006)
Assistant Professor of Chemistry

University of California, Berkeley, CA (2003 – 2004)
Postdoctoral Research Associate

Publications

"Correlations Between Nucleophilicities and Selectivities in the Substitutions of Tetrahydropyran Acetals," J.R. Krumper, W.A. Salamant, and K.A. Woerpel, Journal of Organic Chemistry, accepted.

“Continuum of Mechanisms for Nucleophilic Substitutions of Cyclic Acetals,” J. R. Krumper, W. A. Salamant, and K. A. Woerpel, Organic Letters, 2008, 10, 4907-4910.

“Analysis of an Unprecedented Mechanism for the Catalytic Hydrosilylation of Carbonyl Compounds,” K. A. Nolin, J. R. Krumper, M. D. Pluth, R. G. Bergman, and F. Dean Toste, Journal of the American Chemical Society 2007, 129, 14684-14696.

“Synthesis and Reactivity of the Hydrido- and Alkylrhenium Methylidene Complexes Cp*(PMe3)2(R)Re=CH2, (R = H, CH3),” J. R. Krumper, R. L. Martin, P. J. Hay, C. M. Yung, J. Veltheer, and R. G. Bergman, Journal of the American Chemical Society 2004, 126, 14804-14815.

“Unusual Ar-H/Rh-H JHH NMR Coupling in Complexes of Rhodium(III): Experimental Evidence and Theoretical Support for an η1-Arene Structure” J. R. Krumper, M. Gerisch, A. Magistrato, U. Röthlisberger, R. G. Bergman, and T. D. Tilley, Journal of the American Chemical Society 2004, 126, 12492-12502.

“Sodium tetrakis(3,5-bis(trifluoromethyl)phenyl)borate, Na[B(3,5-(CF3)2C6H3)4]” D. L. Reger, C. A. Little, J. J. S. Lamba, K. J. Brown, J. R. Krumper, R. G. Bergman, M. Irwin, J. P. Fackler, Jr., Inorganic Syntheses, 2004, 34, 5-8.

“Monomeric Rhodium(II) Catalysts for the Preparation of Aziridines and Enantioselective Formation of Cyclopropanes from Ethyl Diazoacetate at Room Temperature” J. R. Krumper, M. Gerisch, J. M. Suh, R.G. Bergman, and T. D. Tilley, Journal of Organic Chemistry 2003, 68, 9705-9710.

“Rhodium(III) and Rhodium(II) Complexes of Novel Bis(oxazoline) Pincer Ligands” M. Gerisch, J. R. Krumper, R. G. Bergman, and T. D. Tilley Organometallics, 2003, 22, 47-58.

“Novel Bis(oxazoline) Pincer Ligands: Formation of Mononuclear Rhodium(II) Complexes” M. Gerisch, J. R. Krumper, R. G. Bergman, and T. D. Tilley Journal of the American Chemical Society 2001, 123, 5818-5819.

Selected Presentations

“Progress Toward Development of Rhenium Catalysts for the Conversion of Epoxides to Aziridines,” M. Moreno, A. W. Fielding, and J. R. Krumper*, Contributed Poster, CHED-933, 231st National Meeting of the American Chemical Society, Atlanta, GA, March 2006.

“New Boryl Ligands for C-H Activation Reactions,” D.X. Denty and J. R. Krumper*, Contributed Poster, CHED-923, 231st National Meeting of the American Chemical Society, Atlanta, GA, March 2006.

“Structural, Mechanistic, and Catalytic Studies of Organometallic Rhodium and Rhenium Complexes,” J. R. Krumper, Wooster College, Stanford University, University of Rhode Island, Idaho State University, University of Illinois, Urbana-Champaign, Emory University, Georgia Institute of Technology, University of California, Irvine; December 2003 – January 2004.

“Rhodium(III) and Rhodium(II) Complexes of Novel Bis(oxazoline) Pincer Ligands,” J. R. Krumper, M. Gerisch, R. G. Bergman, and T. D. Tilley, Poster, Gordon Conference on Organometallic Chemistry, Summer

“Synthesis, Reactivity, and Theoretical Studies of Cationic Re(III) Methyl and Hydrido Methylene Complexes,” J. R. Krumper, P. J. Hay, R. L. Martin, and R. G. Bergman, Contributed Talk, INOR-521, 220th National Meeting of the American Chemical Society, Washington D.C., August 2000.